Syntheses, structures, and properties of Ni(II) complexes with 5,5′-bis(4-halogenphenyl)diazo-dipyrromethane

被引：11

作者：

Yin, Zhenming ^{[1
]}

Yan, Ying ^{[1
]}

Sun, Shipeng ^{[1
]}

Wang, Wuyan ^{[1
]}

机构：

[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 05期

关键词：

Diazo-dipyrromethane; Metal complex; Azo-hydrazone tautomerism; C-H center dot center dot center dot Ni interaction; HOMOCHIRAL M-HELIX; C-H; SPECTRAL CHARACTERIZATION; AZO DYES; ZN-II; NI-II; COORDINATION; LIGANDS; DESIGN; CYTOTOXICITY;

D O I：

10.1080/00958972.2012.663493

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ni(II) complexes with 5,5'-bis(4-halogenphenyl)diazo-dipyrromethane have been synthesized and characterized by X-ray crystallography. All the complexes have similar crystal structures in which Ni(II) is square-planar by coordinating to two pyrrole and two azo nitrogen atoms. The azo-pyrroles of the ligands can be converted to the hydrazone tautomer after complexing nickel. Moreover, the C-H center dot center dot center dot Ni interaction played an important role in directing self-assembly of the complexes. The UV-Vis spectra of the complexes showed great difference with the metal complexes of pyrrol-2-imine.

引用

页码：865 / 874

页数：10

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