Solvation and Stabilization of Metallic Nanoparticles in Ionic Liquids

被引：122
|
作者：
Pensado, Alfonso S. [1 ,2 ]
Padua, Agilio A. H. [1 ,2 ]
机构：
[1] Univ Blaise Pascal Clermont Ferrand, Lab Thermodynam & Interact Mol, F-63171 Aubiere, France
[2] CNRS, F-63171 Aubiere, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 37期
关键词：
ionic liquids; molecular interactions; molecular simulations; nanoparticles; solvation; SIZE-DEPENDENT FORMATION; GAUSSIAN-BASIS SETS; DISSOCIATIVE CHEMISORPTION; RUTHENIUM NANOPARTICLES; ATOMS LI; SURFACE; ORGANIZATION;
D O I：
10.1002/anie.201103096
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Not thick-skinned: The solvation of a metallic nanoparticle in the ionic liquid [C 4C 1im][Ntf 2] was investigated by molecular simulation with a specific interaction potential. The interfacial layer of ionic liquid is only one ion thick, and thus excludes a stabilization mechanism based on an electrostatic double layer. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8683 / 8687
页数：5
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