Fourier-transform infrared and Raman spectra of glutarimide

被引：3

作者：

Leroux, N ^{[1
]}

Zeegers-Huyskens, T ^{[1
]}

机构：

[1] Univ Louvain, Dept Chem, B-3001 Heverlee, Belgium

来源：

SPECTROSCOPY LETTERS | 1999年 / 32卷 / 01期

关键词：

polycrystalline glutarimide; FT IR and Raman spectra; hydrogen bond; temperature effect;

D O I：

10.1080/00387019909349966

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The FT-IR ( from 50 to - 180 degrees C) and the FT-Raman spectra at 25 degrees C of glutarimide in iu the solid state are investigated. The data are compared with recent results of Bienko et al.( J.Phys.Chem.A 101,7834 (1997) on glutarimide isolated in a low-temperature argon matrix. The vibrational changes induced by hydrogen bond formation in the crystalline state are discussed. The v(NH...O) vibration is observed at 3189 cm(-1) at 25 degrees C and at 3163 cm(-1) at - 180 degrees C. These values correspond to a contraction of the N...O distance of 0.022 Angstrom.

引用

页码：47 / 56

页数：10

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