Correlated dynamics of electrons with reduced two-electron density matrices

被引:14
|
作者
Schaefer-Bung, B. [1 ]
Nest, M. [1 ]
机构
[1] Univ Potsdam, Inst Chem, D-14476 Potsdam, Germany
来源
PHYSICAL REVIEW A | 2008年 / 78卷 / 01期
关键词
D O I
10.1103/PhysRevA.78.012512
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We present an approach to the correlated dynamics of many-electron systems. We show, that the two-electron reduced density matrix (2RDM) can provide a suitable description of the real time evolution of a system. To achieve this, the hierarchy of equations of motion must be truncated in a practical way. Also, the computational effort, given that the 2RDM is represented by products of two-electron determinants, is discussed, and numerical model calculations are presented.
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页数:6
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