[μ-2-(4-Hydroxyphenyl)acetato]-κ3O:O,O′;κ3O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]holmium(III)} monohydrate

被引：1
|
作者：
Liu, Jia-Lu
Liu, Jian-Feng
Zhao, Guo-Liang [1 ]
机构：
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811001115
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title dinuclear complex, [Ho-2(C8H7O3)(6)(C10H8N2)(2)(H2O)(2)]center dot H2O, each of the two independent Ho-III ions is coordinated by eight O atoms from four 4-hydroxyphenyl-acetate (HPAA) ligands and a water molecule, and one N atom from a 4,4'-bipyridine (bipy) ligand in a distorted tricapped trigonal-prismatic geometry. The HPAA ligands are coordinated in bis-chelate, bridging and bridging tridentate modes. In the crystal, O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds link the molecules into a three-dimensional network.
引用
收藏
页码：M191 / U781
页数：24
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