[μ-2-(4-Hydroxyphenyl)acetato]-κ3O:O,O′;κ3O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O′]holmium(III)} monohydrate

被引：1

作者：

Liu, Jia-Lu

Liu, Jian-Feng

Zhao, Guo-Liang ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S1600536811001115

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title dinuclear complex, [Ho-2(C8H7O3)(6)(C10H8N2)(2)(H2O)(2)]center dot H2O, each of the two independent Ho-III ions is coordinated by eight O atoms from four 4-hydroxyphenyl-acetate (HPAA) ligands and a water molecule, and one N atom from a 4,4'-bipyridine (bipy) ligand in a distorted tricapped trigonal-prismatic geometry. The HPAA ligands are coordinated in bis-chelate, bridging and bridging tridentate modes. In the crystal, O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds link the molecules into a three-dimensional network.

引用

页码：M191 / U781

页数：24

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[1] Bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)-acetato-κ2O,O′]erbium(III)} monohydrate
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[7] Tetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2O,O]neodymium(III)} monohydrate
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[9] catena-Poly[[[diaqua(nitrato-κ2O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ3O,O′:O;κ3O:O,O′] monohydrate]
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[10] Bis(μ-acetato-κ3O,O′:O′)bis[bis(acetato-κ 2O,O′)diaquadysprosium(III)] tetrahydrate
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