A three-dimensional hydrogen-bonded framework in 2-amino-6-(N-methyl-anilino)pyrimidin-4(3H)-one and a ribbon of fused hydrogen-bonded rings in 2-amino-6-(N-methylanilino)-5-nitropyrimidin-4(3H)-one

被引：2
|
作者：
Rodriguez, Ricaurte
Cobo, Justo
Nogueras, Manuel
Low, John N.
Glidewell, Christopher [1 ]
机构：
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Jaen, Dept Quim Inorgan & Organ, Jaen 23071, Spain
[3] Univ Aberdeen, Dept Chem, Old Aberdeen AB24 3UE, Scotland
[4] Univ Nacl Colombia, Dept Chem, Bogota 14490, Colombia
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2007年 / 63卷 / 12期
关键词：
Electronic structure - Hydrogen bonds - Molecular structure - Polarization;
D O I：
10.1107/S0108270107049931
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The molecular dimensions of both 2-amino-6-(N-methylanilino) pyrimidin-4(3H)-one, C11H12N4O, (I), and 2-amino-6-(N-methylanilino)-5-nitropyrimidin-4(3H)-one, C11H11N5O3, (II), are consistent with considerable polarization of the molecular-electronic structures. The molecules of (I) are linked into a three-dimensional framework by a combination of one N-H center dot center dot center dot N hydrogen bond, two independent N H center dot center dot center dot O hydrogen bonds and one C-H center dot center dot center dot pi(arene) hydrogen bond. The molecules of (II) are linked into ribbons containing three types of edge-fused ring by the combination of two independent three-centre N-H center dot center dot center dot(O)(2) hydrogen bonds.
引用
收藏
页码：O697 / O700
页数：4
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