Synthesis and Physical Properties of Cobalt-Zinc Hybrid Porous Metal-organic Frameworks

被引：1

作者：

Shi Baozhen ^{[1
]}

Li Shan ^{[1
]}

Wang Dianpeng ^{[1
]}

Zhou Yunzhi ^{[1
]}

Sun Jinyu ^{[1
]}

机构：

[1] Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2019年 / 40卷 / 12期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

Metal-organic frameworks; Coordination polymer; Heterometal complex; Magnetic property; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; HYDROGEN STORAGE; COMPLEXES; LUMINESCENT; ADSORPTION; CHANNELS; DESIGN;

D O I：

10.7503/cjcu20190395

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coordination polymer ZnCo (BTC) (OH) (H2O)(3) (NMP) (DMF) (H2O)(1.5) was synthesized by slowly diffusing a balanced amount of organic amine into a solution of 1,3, 5-benzenetricarboxylate (H-3 BTC), zinc nitrate and cobalt nitrate. X-ray single crystal diffraction shows that the compound crystallizes in cubic, space group P2(1)3, and its cell parameter is 1. 43863(20) nm. Its physical properties were characterized by elemental analysis (EA), energy-dispersive X-ray spectroscopy (EDS), X-ray powder diffraction (XRD), N-2 sorption and variable-temperature magnetic susceptibility. The gas sorption shows this compound holds I-isotherm characteristic of micropore, which is 0. 84 nm of pore size and 832 m(2)/g of langmiur surface area. The magnetic results show that it exhibits antiferromagnetism in the temperature range of 37-300 K.

引用

页码：2443 / 2447

页数：5

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