A [70]fullerene chloride, C70Cl16, obtained by the attempted bromination of C70 in TiCl4

被引：43
|
作者：
Troyanov, SI [1 ]
Popov, AA [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Leninskie Gory, Russia
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 27期
关键词：
chlorination; density functional calculations; fullerenes; halogen exchange; structure elucidation;
D O I：
10.1002/anie.200500476
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Tales of the unexpected: The [70]fullerene chloride C70Cl16 resulted from the reaction of [70]fullerene with a mixture of Br2 and TiCl4. A single-crystal X-ray crystallographic study revealed the presence of two isomers of C70Cl16, both containing a belt often chlorine atoms around the equator and a skew pyramidal cap of six chlorine atoms on the pole of the C70Cl16 molecule (see picture). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4215 / 4218
页数：4
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