A [70]fullerene chloride, C70Cl16, obtained by the attempted bromination of C70 in TiCl4

被引：43

作者：

Troyanov, SI ^{[1
]}

Popov, AA ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Leninskie Gory, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 27期

关键词：

chlorination; density functional calculations; fullerenes; halogen exchange; structure elucidation;

D O I：

10.1002/anie.200500476

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Tales of the unexpected: The [70]fullerene chloride C70Cl16 resulted from the reaction of [70]fullerene with a mixture of Br2 and TiCl4. A single-crystal X-ray crystallographic study revealed the presence of two isomers of C70Cl16, both containing a belt often chlorine atoms around the equator and a skew pyramidal cap of six chlorine atoms on the pole of the C70Cl16 molecule (see picture). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4215 / 4218

页数：4

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