Synthesis and Structure of Trimethylplatinum(IV) Iodide Complex of 4'-(4-Methoxyphenyl)-2,2':6',2''-terpyridine Ligand and its Halogen Bonding Property

被引：17

作者：

Das, Dipankar ^{[1
]}

Sutradhar, Sourav ^{[1
]}

Rissanen, Kari ^{[2
]}

Ghosh, Biswa Nath ^{[1
,2
]}

机构：

[1] Natl Inst Technol Silchar, Dept Chem, Cachar 788010, Assam, India

[2] Univ Jyvaskyla, Dept Chem, Nanosci Ctr, POB 35, Jyvaskyla 40014, Finland

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2020年 / 646卷 / 05期

关键词：

Halogen bond; Trimethylplatinum(IV); Terpyridine; 1; 4-Diiodotetrafluorobenzene (DITFB); X-ray diffraction; FLUXIONAL BIDENTATE LIGAND; SOLUTION DYNAMICS; HYDROGELATION; CRYSTALS; BR;

D O I：

10.1002/zaac.201900201

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural characterization of a new trimethylplatinum(IV) iodide complex of 4'-(4-methoxyphenyl)-2,2':6',2''-terpyridine ligand L, {PtMe3IL} (1) is reported. The X-ray crystal structure shows that the terpyridine ligand L binds the platinum(IV) metal center in bidentate fashion, which is well supported by the H-1 NMR spectrum of 1. The complex 1 upon crystallization with 1,4-diiodotetrafluorobenzene (DITFB) forms the halogen bonded complex 1a (1 center dot DITFB). The structural investigation shows that 1a exhibits the halogen bonding interaction in which the non-coordinated pyridyl nitrogen acts as halogen bond acceptors by forming I center dot center dot center dot N interaction with iodine atom of DITFB. In addition iodine atom of complex 1 also acts as weak halogen bond acceptor.

引用

页码：301 / 306

页数：6

共 50 条

[41] SYNTHESIS, STRUCTURE, AND TRANSITION-METAL COMPLEXES OF 4'-FERROCENYL-2,2'/6'2''-TERPYRIDINE
FARLOW, BC
NILE, TA
WALSH, JL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 12 - INOR
[42] Spectroscopic study on the 4′-(4-pyridyl)-2,2′:6′,2"-terpyridine and its metal complexes
Zhang, Chao-Feng
Huang, Hong-Xiang
Liu, Bing
Chen, Meng
Qian, Dong-Jin
JOURNAL OF LUMINESCENCE, 2008, 128 (03) : 469 - 475
[43] Chiral 2,2':6',2''-terpyridine ligands for metallosupramolecular chemistry .2. Metal complexes of 4'-([(1S)-endo]-bornyloxy)-2,2':6',2''-terpyridine, 4'-([(1R)-endo]-bornyloxy)-2,2':6',2''-terpyridine, 4'-quniinyl-2,2':6',2''-terpyridine, and 4'-(2,2':6',2''-terpyridinyl)-(1S)-10-camphorsulfonate
Constable, EC
Kulke, T
Neuburger, M
Zehnder, M
NEW JOURNAL OF CHEMISTRY, 1997, 21 (10) : 1091 - 1102
[44] Chiral 2,2':6',2''-terpyridine ligands for metallosupramolecular chemistry .1. Synthesis of ligands and structural characterization of 4'-([(1S)-endo]-bornyloxy)-2,2':6',2''-terpyridine, 4'-([(1R)-endo]-bornyloxy)-2,2':6',2''-terpyridine, 4'-quininyl-epi-quininyl-2,2':6',2''-terpyridine, and 4'-(2,2':6',2''-terpyridinyl)-(1S)-10-camphorsulfonate
Constable, EC
Kulke, T
Neuburger, M
Zehnder, M
NEW JOURNAL OF CHEMISTRY, 1997, 21 (05) : 633 - 646
[45] Carbaborane-functionalised 2,2′:6′,2"-terpyridine ligands for metallosupramolecular chemistry:: Syntheses, complex formation, and the crystal and molecular structures of 4′-(optho-carboranyl)-2,2′:6′,2"-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2"-terpyridine
Armspach, D
Constable, EC
Housecroft, CE
Neuburger, M
Zehnder, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) : 193 - 206
[46] 4′-(4-fluorophenyl)-2,2′:6′,2"-terpyridine -: an aryl-2,2′:6′,2"-terpyridine with an electron-releasing aryl substituent
Constable, EC
Neuburger, M
Smith, DR
Zehnder, M
INORGANICA CHIMICA ACTA, 1998, 276 (1-2) : 359 - 365
[47] Synthesis and theoretical studies of a double helical complex with the ligand 4′,4′′′-Bis(ferrocenyl)-2,2′:6′,2′′′:6′′′,2′′′′-quinquepyridine
Aguado, JE
Calhorda, MJ
Costa, PJ
Crespo, O
Felix, V
Gimeno, MC
Jones, PG
Laguna, A
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (15) : 3038 - 3047
[48] Carbaborane-functionalised 2,2':6',2''-terpyridine ligands for metallosupramolecular chemistry: Syntheses, complex formation, and the crystal and molecular structures of 4'-(ortho-carboranyl)-2,2':6',2''-terpyridine and 4'-(ortho-carboranylpropoxy)-2,2':6',2''-terpyridine
J Organomet Chem, 1 (175):
[49] Crystal structure of a hydroxo-bridged dimeric uranyl complex with a 2,2′:6′,2″-terpyridine ligand
K. Lyczko
L. Steczek
Journal of Structural Chemistry, 2017, 58 : 102 - 106
[50] CRYSTAL STRUCTURE OF A HYDROXO-BRIDGED DIMERIC URANYL COMPLEX WITH A 2,2′:6′,2"-TERPYRIDINE LIGAND
Lyczko, K.
Steczek, L.
JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 58 (01) : 102 - 106

← 1 2 3 4 5 →