Infrared spectroscopy of protonated phenylsilane in the gas phase

被引：31
|
作者：
Chiavarino, B
Crestoni, ME
Fornarini, S [1 ]
Lemaire, J
Mac Aleese, L
Maître, P
机构：
[1] Univ Paris Sud 1, Fac Sci Orsay, CNRS, Chim Phys Lab,UMR8000, F-91405 Orsay, France
[2] Univ Roma La Sapienza, Dipartimento Studi Chim & Tecnol, I-00185 Rome, Italy
来源：
CHEMPHYSCHEM | 2005年 / 6卷 / 03期
关键词：
arenium ions; gas-phase reactions; IR spectroscopy; mass spectroscopy; structure elucidation;
D O I：
10.1002/cphc.200400511
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Gaseous ions: A variant of IR spectroscopy, developed to solve the structure of gaseous ions, was applied to the prototypical silyl-substituted arenium ion, [H3Si-C6H6]+. The experimental IR multiphoton-induced dissociation (IRMPD) spectrum is found to match the IR absorption features calculated for the ipsoprotonated species (see figure). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：437 / 440
页数：4
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