Infrared spectroscopy of protonated phenylsilane in the gas phase

被引：31
|
作者：
Chiavarino, B
Crestoni, ME
Fornarini, S [1 ]
Lemaire, J
Mac Aleese, L
Maître, P
机构：
[1] Univ Paris Sud 1, Fac Sci Orsay, CNRS, Chim Phys Lab,UMR8000, F-91405 Orsay, France
[2] Univ Roma La Sapienza, Dipartimento Studi Chim & Tecnol, I-00185 Rome, Italy
来源：
CHEMPHYSCHEM | 2005年 / 6卷 / 03期
关键词：
arenium ions; gas-phase reactions; IR spectroscopy; mass spectroscopy; structure elucidation;
D O I：
10.1002/cphc.200400511
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Gaseous ions: A variant of IR spectroscopy, developed to solve the structure of gaseous ions, was applied to the prototypical silyl-substituted arenium ion, [H3Si-C6H6]+. The experimental IR multiphoton-induced dissociation (IRMPD) spectrum is found to match the IR absorption features calculated for the ipsoprotonated species (see figure). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：437 / 440
页数：4
相关论文
共 50 条
  • [1] Infrared photodissociation spectroscopy of protonated neurotransmitters in the gas phase
    Macleod, N. A.
    Simons, J. P.
    MOLECULAR PHYSICS, 2006, 104 (20-21) : 3317 - 3328
  • [2] Neurotransmitters in the gas phase: Infrared spectroscopy and structure of protonated ethanolamine
    Macleod, NA
    Simons, JP
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (10) : 2821 - 2826
  • [3] Dissociation routes of protonated toluene probed by infrared spectroscopy in the gas phase
    Schroeder, Detlef
    Schwarz, Helmut
    Milko, Petr
    Roithova, Jana
    JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (27): : 8346 - 8353
  • [4] Gas-phase infrared laser photolysis of phenylsilane
    Nájera, JJ
    Cáceres, JO
    Lane, SI
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2000, 131 (1-3) : 1 - 11
  • [5] Infrared spectroscopy of hydrated amino acids in the gas phase: Protonated and lithiated valine
    Kamariotis, Anthi
    Boyarkin, Oleg V.
    Mercier, Sébastien R.
    Beck, Rainer D.
    Bush, Matthew F.
    Williams, Evan R.
    Rizzo, Thomas R.
    Journal of the American Chemical Society, 2006, 128 (03): : 905 - 916
  • [6] Infrared spectroscopy of hydrated amino acids in the gas phase: Protonated and lithiated valine
    Kamariotis, A
    Boyarkin, OV
    Mercier, SR
    Beck, RD
    Bush, MF
    Williams, ER
    Rizzo, TR
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (03) : 905 - 916
  • [7] Infrared fingerprint of protonated benzene in the gas phase
    Jones, W
    Boissel, P
    Chiavarino, B
    Crestoni, ME
    Fornarini, S
    Lemaire, J
    Maitre, P
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (18) : 2057 - 2059
  • [8] Infrared photodissociation spectroscopy of protonated neurotransmitters in the gas phase (vol 104, pg 3317, 2006)
    Macleod, N. A.
    Simons, J. P.
    MOLECULAR PHYSICS, 2007, 105 (5-7) : I - +
  • [9] infrared spectrum of the protonated water dimer in the gas phase
    Fridgen, TD
    McMahon, TB
    MacAleese, L
    Lemaire, J
    Maitre, P
    JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (42): : 9008 - 9010
  • [10] Infrared spectroscopy of gas phase benzenium ions:: Protonated benzene and protonated toluene, from 750 to 3400 cm-1
    Douberly, G. E.
    Ricks, A. M.
    Schleyer, P. v. R.
    Duncan, M. A.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (22): : 4869 - 4874
12345