Luminescent Coordination Polymers Constructed from a Flexible, Tetradentate Diisopyrazole Ligand and Copper(I) Halides

被引：12
|
作者：
Yoneda, Tomoki [1 ]
Kasai, Chika [1 ]
Manabe, Yumehiro [1 ]
Tsurui, Makoto [1 ]
Kitagawa, Yuichi [1 ,2 ]
Hasegawa, Yasuchika [1 ,2 ]
Sarkar, Parantap [2 ]
Inokuma, Yasuhide [1 ,2 ]
机构：
[1] Hokkaido Univ, Div Appl Chem, Fac Engn, Kita Ku, Kita 13,Nishi 8, Sapporo, Hokkaido 0608628, Japan
[2] Hokkaido Univ, Inst Chem React Design & Discovery WPI ICReDD, Kita Ku, Kita 21,Nishi 10, Sapporo, Hokkaido 0010021, Japan
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2020年 / 15卷 / 05期
关键词：
copper halide; coordination polymer; polyimine; luminescence; STRUCTURAL-CHARACTERIZATION; COMPLEXES; CRYSTAL; TETRANUCLEAR; MOLECULES; CLUSTERS; NETWORK; GEOMETRY; PYRIDINE; SHEET;
D O I：
10.1002/asia.201901682
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One- and two-dimensional coordination polymers composed of a structurally flexible, tetradentate diisopyrazole ligand and copper(I) halides were synthesized as crystalline solids. Complexation with copper(I) chloride or bromide resulted in the formation of infinite coordination chains through connecting each diisopyrazole ligand with two copper(I) ions in a trigonal planar coordination geometry. Contrarily, the combination of a diisopyrazole ligand and copper(I) iodide gave a two-dimensional coordination network comprising Cu4I4 units with stair-step type geometry and diisopyrazoles that acted as both tetradentate and bidentate bridging ligands. All the coordination polymers exhibited visible photo-emission upon UV irradiation, and the Cu4I4 complex showed thermochromic behavior.
引用
收藏
页码：601 / 605
页数：5
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