Cd(II) coordination polymers constructed from flexible disulfide ligand: Solvothermal syntheses, structures and luminescent properties

被引：27
|
作者：
Yu, Jianghua [1 ]
Yao, Rong [1 ]
Yuan, Limin [1 ]
Xu, Bin [1 ]
Qu, Botao [1 ]
Liu, Wenlong [1 ,2 ]
机构：
[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2011年 / 376卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Coordination polymers; 2,2-Dithiobisbenzoic acid; Auxiliary ligands; Luminescence; METAL-ORGANIC FRAMEWORKS; GUEST-EXCHANGE; SUPRAMOLECULAR ISOMERISM; HYDROTHERMAL SYNTHESES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; THERMAL-STABILITY; COMPLEXES; ACID; ARCHITECTURES;
D O I：
10.1016/j.ica.2011.06.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four novel coordination polymers, [Cd(Hdtbb)(dtbb)(0.5)(DMF)](n) (1), {[Cd(dtbb)(2,2'-bpy)(H2O)]center dot 2DMA}(n) (2), {[Cd-2(dtbb)(2)(1,4-bix)(2)]center dot 3DMF}(n) (3) and [Cd(dtbb)(1,4-btx)](n) (4) [H(2)dtbb = 2,2-dithiobisbenzoic acid, 2,2'-bpy = 2,2'-bipyridine, 1,4-bix = 1,4-bis(imidazol-1-ylmethyl)benzene, 1,4-btx = 1,4-bis(triazol-1-yl-methyl)benzene] have been synthesized and structurally characterized. Complexes 1 and 2 possess one-dimensional (1D) infinite structures. The structures of complexes 3 and 4 exhibit two dimensional (2D) frameworks, which mainly due to the differences in the bridging modes of dtbb(2) ligand and the effect of the N-donor auxiliary ligands. The infrared spectra, thermogravimetric and luminescent properties were also investigated for these compounds. (C) 2011 Elsevier B. V. All rights reserved.
引用
收藏
页码：222 / 229
页数：8
相关论文
共 50 条
  • [1] In situ ligand generation for novel Mn(II) and Ni(II) coordination polymers with disulfide ligand: Solvothermal syntheses, structures and magnetic properties
    Han, Yinfeng
    Wang, Chang'an
    Zheng, Zebao
    Sun, Jiafeng
    Nie, Kun
    Zuo, Jian
    Zhang, Jianping
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2015, 227 : 87 - 91
  • [2] Syntheses, structures and luminescence of a series of Cd(II)-containing coordination polymers constructed from a long flexible bis-triazole ligand
    Mu, Yajuan
    Song, Yajing
    Wang, Chan
    Hou, Hongwei
    Fan, Yaoting
    [J]. INORGANICA CHIMICA ACTA, 2011, 365 (01) : 167 - 176
  • [3] Two Low Dimensional Cd(II) Coordination Polymers Constructed from Zwitterionic Dicarboxylate Ligand: Syntheses, Structures, and Fluorescent Properties
    Ding Fang-Fang
    Zhang Na
    Zhang Jian-Yong
    Wang Min
    Gao En-Qing
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2015, 31 (10) : 1929 - 1937
  • [4] Hydrothermal syntheses, crystal structures, and properties of two new coordination polymers constructed from a flexible pyridinecarboxylate ligand
    Xing, Guang'en
    Zhang, Yan
    Zhang, Sufang
    Dong, Yanli
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (11) : 2006 - 2013
  • [5] Two Cd(II) Coordination Polymers Based on a Flexible Tricarboxylate Ligand: Syntheses, Structures, and Photoluminescence and Catalytic Properties
    Zhu En-Wei
    Sun Jun-Jie
    Jia Yu
    Qiao Yu
    Zhu Yu
    Che Guang-Bo
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37 (12) : 2003 - 2010
  • [6] Syntheses, Structures, and Luminescent Properties of Six New Zinc(II) Coordination Polymers Constructed by Flexible Tetracarboxylate and Various Pyridine Ligands
    Zhang, Xin
    Hou, Lei
    Liu, Bo
    Cui, Lin
    Wang, Yao-Yu
    Wu, Biao
    [J]. CRYSTAL GROWTH & DESIGN, 2013, 13 (07) : 3177 - 3187
  • [7] Solvothermal syntheses, crystal structures, thermal and photoluminescent properties of four coordination polymers constructed from mercapto-thiadiazole ligand
    Li, Linke
    Wei, Lulu
    Si, Xiaoqin
    Fan, Liyan
    Wang, Changhong
    Hou, Hongwei
    [J]. INORGANICA CHIMICA ACTA, 2013, 405 : 279 - 287
  • [8] Syntheses, crystal structures and photoluminescence of two Cd(II) coordination polymers derived from a flexible bipyridyl ligand
    Gong, YQ
    Wang, RH
    Zhou, YF
    Yuan, DQ
    Hong, MC
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2004, 705 (1-3) : 29 - 34
  • [9] Copper(II) coordination polymers constructed from flexible ligands with different spacer lengths: syntheses, structures, and properties
    Tian, Li
    Zhou, Shang Yong
    Xu, Ming Yuan
    Wang, Li Ping
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (21) : 3792 - 3804
  • [10] Syntheses, structures, luminescent and magnetic properties of two coordination polymers based on a flexible multidentate carboxylate ligand
    Tian, Dan
    Liu, Xiao-Jing
    Chen, Rong-Ying
    Zhang, Ying-Hui
    [J]. CHINESE CHEMICAL LETTERS, 2015, 26 (05) : 499 - 503
12345