Synthesis and spectroscopic properties of β-meso directly linked porphyrin-corrole hybrid compounds

被引：7
|
作者：
Temelli, Baris [1 ]
Kalkan, Hilal [1 ]
机构：
[1] Hacettepe Univ, Dept Chem, Beytepe Campus, TR-06800 Ankara, Turkey
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 14卷
关键词：
corrole; hybrid compounds; indium(III) chloride; porphyrin; porphyrinoids; PHOTOINDUCED CHARGE SEPARATION; MESOSUBSTITUTED CORROLES; ELECTRON-TRANSFER; DYADS; CONJUGATE; SPECTROELECTROCHEMISTRY; ELECTROCHEMISTRY; BINDING; SYSTEM; TRIAD;
D O I：
10.3762/bjoc.14.13
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The preparation of beta-meso directly linked porphyrin-corrole hybrids was realized for the first time via an InCl3-catalyzed condensation reaction of 2-formyl-5,10,15,20-tetraphenylporphyrins with meso-substituted dipyrromethanes. Hybrid compounds have been characterized by H-1 NMR, C-13 NMR, 2D NMR, UV-vis absorption and fluorescence spectroscopy.
引用
收藏
页码：187 / 193
页数：7
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