The Cu(OTf)2- and Yb(OTf)3-catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers

被引：37
|
作者：
Hiersemann, M [1 ]
Abraham, L [1 ]
机构：
[1] Tech Univ Dresden, Inst Organ Chem, D-01062 Dresden, Germany
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 01期
关键词：
D O I：
10.1021/ol006760w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] The Cu(OTf)(2)- and Yb(OTf)(3)-catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers has been developed. Reactivity and stereoselectivity strongly depend on the substrate structure.
引用
收藏
页码：49 / 52
页数：4
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