Phenyl-functionalized diiron propanediselenolato complexes containing intramolecular bridging diphosphine ligands

被引：4

作者：

Xu, Guang-Ri ^{[1
]}

Liu, Lu ^{[1
]}

Gao, Hui-Ling ^{[1
]}

Shang, Jing-Yan ^{[1
]}

Li, Chang-Gong ^{[1
]}

机构：

[1] Henan Inst Sci & Technol, Coll Chem & Chem Engn, Xinxiang, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2017年 / 70卷 / 15期

关键词：

Fe-Fe]-hydrogenase; bidentate phosphine ligand; crystal structure; BIDENTATE PHOSPHINE-LIGANDS; ACTIVE-SITE MODELS; PROPANEDITHIOLATE COMPLEXES; PROTON-REDUCTION; DITHIOLATE COMPLEXES; DISELENOLATO COMPLEXES; ONLY HYDROGENASE; IRON HYDROGENASE; CATALYSIS; MIMICS;

D O I：

10.1080/00958972.2017.1356921

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [(-SeCH2)(2)CHC6H5]Fe-2(CO)(6) (A) with 1,1-bis(diphenylphosphino)ferrocene (dppf) or 1,3-bis(diphenylphosphino)propane (dppp) in refluxing xylene yielded [(-SeCH2)(2)CHC6H5]Fe-2(CO)(4)(-dppf) (1) or [(-SeCH2)(2)CHC6H5]Fe-2(CO)(4)(-dppp) (2) in moderate yields. The chemical structures of both complexes were characterized by spectroscopic methods and X-ray crystallography, and the electronic structures were further investigated by UV-vis. The redox properties of both complexes in the absence and presence of acetic acid were observed by cyclic voltammetry (CV). [GRAPHICS] .

引用

页码：2684 / 2694

页数：11

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