Hydrothermal Synthesis and Structural Characterization of a New Keggin-Type Tungstogermanate Containing Heterometallic 3d-4f Cubane Clusters

被引：22
|
作者：
Wang, Wei-Dong [1 ]
Li, Xin-Xiong [1 ]
Fang, Wei-Hui [1 ]
Yang, Guo-Yu [1 ]
机构：
[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 2011年 / 22卷 / 01期
关键词：
Hydrothermal synthesis; Lacunary polyoxometalate; Heterometallic cubane; Germanate; SANDWICH-TYPE POLYOXOMETALATE; TRANSITION-METAL CLUSTERS; LANTHANIDE; FRAMEWORK; POLYOXOTUNGSTATES; COMBINATION; AGGREGATE; CENTERS; CHAINS; DIMER;
D O I：
10.1007/s10876-011-0351-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Keggin-type 3d-4f heterometallic incorporated polyoxotungstate, {[Cu(en)(2)(H2O)][DyCu3(en)(3)(OH)(3)(H2O)(2)(GeW11O39)]}(2)center dot 18H(2)O (1) (en = ethylenediamine), has been hydrothermally synthesized and characterized by IR spectroscopy, TG, and single-crystal X-ray diffraction. Structure analysis revealed that the dimeric compound 1 contains {DyCu3(OH)(3)O} cubane fragments and represents the first tungstogermanate with heterometallic 3d-4f cubane cluster.
引用
收藏
页码：87 / 95
页数：9
相关论文
共 50 条
  • [41] Structural Extension from 0D to 3D Pillared Heterometallic 3d-4f Polyoxometalate Hybrids
    Yao, Wei
    Liu, Li
    Wang, Xinlong
    Qin, Chao
    Su, Zhongmin
    CRYSTAL GROWTH & DESIGN, 2020, 20 (04) : 2706 - 2712
  • [42] Hydrothermal syntheses and crystal structures of a series of 3d-4f heterometallic tetrazole-based coordination polymers
    Liang, Li
    Li, Guizhu
    Sun, Lin
    Lan, Guoqiang
    Zhang, Limin
    Yang, Chengfeng
    Ma, Yingzhao
    Deng, Hong
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 20 : 295 - 298
  • [43] Hydrothermal synthesis and crystal structure of a new 3d-4f complex generated from the IDA ligand
    Zhang, P.
    Li, Y.
    Wang, F. Z.
    Yang, Q.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (10) : 784 - 788
  • [44] Iminodiacetic acid stabilized 3d-4f clusters: Synthesis, structure, and magnetism
    Qi, Ming-Qiang
    Zhang, Hong-Tai
    Diao, Xin-Ya
    Kong, Xiang-Jian
    Long, La-Sheng
    Zheng, Lan-Sun
    COORDINATION CHEMISTRY REVIEWS, 2025, 534
  • [45] Synthesis, Crystal Structure and Characterization of 3d-4d-4f Heterometallic Clusters Based on Super Tetrahedron Anions
    Wu, Shu-Ting
    Lu, Shu-Mei
    Tang, Hong-Liang
    Deng, Bin-Bin
    Huang, Xi-He
    Huang, Chang-Cang
    JOURNAL OF CLUSTER SCIENCE, 2014, 25 (05) : 1413 - 1424
  • [46] Structural Diversity of Infinite 3d-4f Heterometallic Cluster Compounds Driven by Various Lanthanide Radii
    Xiang, Shengchang
    Hu, Shengmin
    Sheng, Tianlu
    Chen, Jianshan
    Wu, Xintao
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (45) : 12496 - 12502
  • [47] SMM behaviour and magnetocaloric effect in heterometallic 3d-4f coordination clusters with high azide : metal ratios
    Schmidt, Sebastian F. M.
    Merkel, Marcel P.
    Kostakis, George E.
    Buth, Gernot
    Anson, Christopher E.
    Powell, Annie K.
    DALTON TRANSACTIONS, 2017, 46 (45) : 15661 - 15665
  • [48] A new 3d-4f heterometallic selenite chloride with a distorted Shastry-Sutherland lattice
    Xie, Yaxin
    He, Zhangzhen
    Zhang, Wanwan
    Zhao, Zhiying
    Zhang, Mengsi
    Huang, Xing
    JOURNAL OF SOLID STATE CHEMISTRY, 2020, 286 (286)
  • [49] Double-Propeller-like Heterometallic 3d-4f Clusters Ln18Co7
    Lun, Hui-Jie
    Du, Ming-Hao
    Wang, Dong-Hui
    Kong, Xiang-Jian
    Long, La-Sheng
    Zheng, Lan-Sun
    INORGANIC CHEMISTRY, 2020, 59 (12) : 7900 - 7904
  • [50] Four 3d-4f heterometallic Ln45M7 clusters protected by mixed ligands
    Fan, Shen
    Xu, Su-Hui
    Zheng, Xiu-Ying
    Yan, Zhi-Hao
    Kong, Xiang-Jian
    Long, La-Sheng
    Zheng, Lan-Sun
    CRYSTENGCOMM, 2018, 20 (15): : 2120 - 2125
12345