μ2-Oxalato-κ2O,O′:κ2O",O"′-bis[aqua(1,10-phenanthroline-κ2 N, N′) copper(II)] dinitrate dihydrate

被引:13
|
作者
Zhang, XD [1 ]
Zhao, Z
Sun, JY
Ma, YC
Zhu, ML
机构
[1] Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
[2] Shanxi Univ, Inst Mol Sci, Key Lab Chem Biol & Mol Engn, Educ Minist, Taiyuan 030036, Shanxi, Peoples R China
关键词
D O I
10.1107/S1600536805037396
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title complex, [Cu-2(C2O4)(C12H8N2)(2)( H2O)(2)](NO3)(2)(.)-2H(2)O, is a centrosymmetric oxalate-bridged binuclear Cu-II complex with an inversion center located at the mid-point of the C - C bond of the bridging oxalate ligand. The Cu atom has five-coordinate square-pyramidal geometry. A network of O - (HO)-O-... hydrogen bonds helps to consolidate the crystal packing.
引用
收藏
页码:M2643 / M2645
页数:3
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