Sensitive Energetics from the N-Amination of 4-Nitro-1,2,3-Triazole

被引：11

作者：

Wozniak, Dominique R. ^{[1
]}

Salfer, Benjamin ^{[2
]}

Zeller, Matthias ^{[3
]}

Byrd, Edward F. C. ^{[4
]}

Piercey, Davin G. ^{[1
]}

机构：

[1] Purdue Univ, Dept Mat Engn, Dept Mech Engn, W Lafayette, IN 47904 USA

[2] Purdue Univ, Dept Chem Engn, 610 Purdue Mall, W Lafayette, IN 47907 USA

[3] Purdue Univ, Dept Chem, 560 Oval Dr, W Lafayette, IN 47907 USA

[4] US Army Res Lab, Aberdeen Proving Ground, MD 21500 USA

来源：

CHEMISTRYOPEN | 2020年 / 9卷 / 08期

基金：

美国国家科学基金会;

关键词：

amination reactions; energetic materials; heterocycles; N-amines; primary explosives; MOLECULAR-ORBITAL METHODS; NITROPYRAZOLES; DETONATION; SPECTRA; ENERGY;

D O I：

10.1002/open.202000053

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Energetic N-amino-C-nitro compounds 1-amino-4-nitro-1,2,3-triazole and 2-amino-4-nitro-1,2,3-triazole are characterized for the first time as energetic materials. These compounds were characterized chemically by nuclear magnetic resonance (NMR), Infrared spectroscopy and X-ray crystallography. Compounds were also characterized energetically by differential scanning calorimetry (DSC), impact, and friction and found to possess sensitivities and performances classifying them as primary explosives with PETN-like performance.

引用

页码：806 / 811

页数：6

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