Synthesis and Characterization of Mesoporous Silicon Spheres from Solid Silica Spheres

被引:0
|
作者
Zhu, Jiang [1 ]
Meng, Changgong [1 ]
机构
[1] Dalian Univ Technol, Dept Chem, Dalian 116023, Peoples R China
关键词
porous silicon; mesoporous; sphere; magnesiothermal; polycrystal; REDUCTION; SI;
D O I
10.4028/www.scientific.net/MSF.675-677.1069
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A well known method was used to convert the solid silica spheres to porous silicon spheres with high surface area, with the starting shape retained. The presented work demonstrated that the porous silicon spheres are composed of polycrystal morphology. Due to the quantum confinement effect, the photoluminescence emission centered at 621 nm. The results of N-2 adsorption and desorption analysis indicates the mesoporous silicon spheres possess a surface area around 88 m(2) g(-1) and single point micro-pore volume 0.173 cm(3) g(-1).
引用
收藏
页码:1069 / 1072
页数:4
相关论文
共 50 条
  • [21] Catalytic characterization of mesoporous Ti-silica hollow spheres
    Baca, M.
    Li, W. J.
    Du, P.
    Mul, G.
    Moulijn, J. A.
    Coppens, M. -O.
    CATALYSIS LETTERS, 2006, 109 (3-4) : 207 - 210
  • [22] Synthesis of silicon dioxide, silicon, and silicon carbide mesoporous spheres from polystyrene sphere templates
    Lauren S. White
    Julia Migenda
    Xiaonan Gao
    Dustin M. Clifford
    Massimo F. Bertino
    Khaled M. Saoud
    Christoph Weidmann
    Bernd M. Smarsly
    Journal of Sol-Gel Science and Technology, 2015, 74 : 575 - 584
  • [23] Synthesis of silicon dioxide, silicon, and silicon carbide mesoporous spheres from polystyrene sphere templates
    White, Lauren S.
    Migenda, Julia
    Gao, Xiaonan
    Clifford, Dustin M.
    Bertino, Massimo F.
    Saoud, Khaled M.
    Weidmann, Christoph
    Smarsly, Bernd M.
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2015, 74 (03) : 575 - 584
  • [24] Mesoporous Silica Spheres as Microreactors for Performing CdS Nanocrystal Synthesis
    Li, Yaoxia
    Zhu, Yihua
    Yang, Xiaoling
    Li, Chunzhong
    CRYSTAL GROWTH & DESIGN, 2008, 8 (12) : 4494 - 4498
  • [25] Synthesis of Monodispersed Mesoporous Spheres of Submicron Size Amorphous Silica
    Trofimova, E. Yu.
    Kurdyukov, D. A.
    Kukushkina, Yu. A.
    Yagovkina, M. A.
    Golubev, V. G.
    GLASS PHYSICS AND CHEMISTRY, 2011, 37 (04) : 378 - 384
  • [26] Hydrothermal synthesis of mesoporous silica spheres: effect of the cooling process
    Yu, Qiyu
    Hui, Junfeng
    Wang, Pengpeng
    Xu, Biao
    Zhuang, Jing
    Wang, Xun
    NANOSCALE, 2012, 4 (22) : 7114 - 7120
  • [27] Synthesis of monodispersed mesoporous spheres of submicron size amorphous silica
    E. Yu. Trofimova
    D. A. Kurdyukov
    Yu. A. Kukushkina
    M. A. Yagovkina
    V. G. Golubev
    Glass Physics and Chemistry, 2011, 37 : 378 - 384
  • [28] Synthesis of nanoscale mesoporous silica spheres with controlled particle size
    Nooney, RI
    Thirunavukkarasu, D
    Chen, YM
    Josephs, R
    Ostafin, AE
    CHEMISTRY OF MATERIALS, 2002, 14 (11) : 4721 - 4728
  • [29] Synthesis of ordered mesoporous silica spheres with controllable diameter in micrometer
    Lei, J
    Yu, CZ
    Fan, J
    Yan, Y
    Tu, B
    Zhao, DY
    ACTA CHIMICA SINICA, 2005, 63 (08) : 739 - 744
  • [30] Synthesis of uniform mesoporous silica spheres with hexagonal symmetry.
    Yano, K
    Fukushima, Y
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : A84 - A84