Thermal stability of glasses from the Fe4(P2O7)3-Fe(PO3)3 system

被引：23
|
作者：
Zhang, Liying [1 ]
Ghussn, Luciana [2 ]
Schmitt, Melodie L. [1 ]
Zanotto, Edgar D. [2 ]
Brow, Richard K. [1 ]
Schlesinger, Mark E. [1 ]
机构：
[1] Missouri Univ Sci & Technol, Dept Mat Sci & Engn, Rolla, MO USA
[2] Univ Fed Sao Carlos, Dept Mat Engn, BR-13560 Sao Carlos, SP, Brazil
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 2010年 / 356卷 / 52-54期
关键词：
Iron phosphate glass; Ferric pyrophosphate; Ferric metaphosphate; Glass stability; IRON PHOSPHATE; STRUCTURAL FEATURES;
D O I：
10.1016/j.jnoncrysol.2010.03.044
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Iron phosphate glasses with nominal Fe/P compositions between 0.50 and 0.67 were prepared and characterized. The effects of melt conditions and the initial composition on the Fe(II)-content are reported. Characteristic temperatures, including the glass transition temperature and crystallization temperature, were measured by DSC. The stability of melts against crystallization, described by the Angel and Weinberg parameters, generally decreases with increasing O/P and Fe/P ratios. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：2965 / 2968
页数：4
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