Catalytic activity and recyclability of new enantioselective chiral Co-salen complexes in the hydrolytic kinetic resolution of epichlorohydrine

被引：37
|
作者：
Kim, GJ [1 ]
Lee, H
Kim, SJ
机构：
[1] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
[2] RS Tech Corp, Taejon 306230, South Korea
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 27期
关键词：
D O I：
10.1016/S0040-4039(03)01182-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Chiral Co(III) salen catalysts bearing PF6, BF4 or Br counterions proved to be reactive and enantioselective in the hydrolytic resolution of terminal epoxides. The catalysts could be recovered and reused several times without further treatment after reaction, showing no loss of activity and enantioselectivity. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：5005 / 5008
页数：4
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