Superlattices of iron nanocubes synthesized from Fe[N(SiMe3)2]2

被引：445

作者：

Dumestre, F

Chaudret, B

Amiens, C

Renaud, P

Fejes, P

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 04, France

[2] Digital DNA Labs, Semicond Prod Sector, F-31023 Toulouse, France

[3] Motorola Inc, Semicond Prod Sector, Digital DNA Labs, Tempe, AZ 85824 USA

来源：

SCIENCE | 2004年 / 303卷 / 5659期

关键词：

D O I：

10.1126/science.1092641

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The reaction of the metal-organic precursor Fe[N(SiMe3)(2)](2) with H-2 in the presence of a long-chain acid and a long-chain amine in various proportions produces monodisperse zerovalent iron nanoparticles. These Fe particles display magnetic properties that match those of bulk iron as evidenced by magnetic and Mossbauer measurements. The nanoparticles adopt a cubic shape with edges of 7 nanometers and are incorporated into extended crystalline superlattices containing nanocubes in close proximity and with their crystallographic axes aligned. These superlattices are formed in solution, precipitate in high yield, and may be redissolved and redeposited as two-dimensional arrays.

引用

页码：821 / 823

页数：3

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