Synthesis of Im3[Mo3(μ3-S)(μ-S2)3Br6]Br (Im=1-ethyl-3-methylimidazolium) in Ionic Liquid: A New Way of Breaking Up Chalcogenide Cluster Coordination Polymers

被引：2

作者：

Sokolov, M. N. ^{[1
,2
]}

Rogachev, A. V. ^{[1
]}

Virovets, A. V. ^{[1
]}

Piryazev, D. A. ^{[1
]}

Fedin, V. P. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

JOURNAL OF CLUSTER SCIENCE | 2015年 / 26卷 / 01期

关键词：

Molybdenum; Chalcogenide clusters; Coordination polymers; Ionic liquid; X-ray structure; CHARGE-TRANSFER SALTS; CRYSTAL-STRUCTURE; COMPLEXES; MO; MO3S7; DITHIOLATE; OXALATE; ROUTE; BR; CL;

D O I：

10.1007/s10876-014-0739-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 1D cluster coordination polymer Mo3S7Br4 with an ionic liquid composed of 1-ethyl-3-methylimidazolium bromide (ImBr) and AlBr3 in 2:1 molar ratio affords Im(3)[Mo-3(mu(3)-S)(mu-S-2)(3)Br-6]Br (1) in high yield. X-ray structure of 1 center dot CH (3) CN is reported.

引用

页码：33 / 40

页数：8

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