Solid-state 31P and 109Ag CP/MAS NMR as a powerful tool for studying of silver(I) complexes with N-thiophosphorylated thiourea and thioamide ligands

被引：0

作者：

Rakhmatullin, Aydar ^{[1
]}

Brusko, Vasiliy V. ^{[2
]}

Shcherbitskaya, Elmira R. ^{[3
]}

Polovov, Ilya B. ^{[4
]}

Bakirov, Rinat ^{[5
]}

Bessada, Catherine ^{[1
]}

机构：

[1] Univ Orleans, UPR CNRS 3079, CEMHTI, Condit Extremes & Mat Haute Temp & Irradiat, F-45071 Orleans, France

[2] Kazan VI Lenin State Univ, AM Butlerov Chem Inst, Kazan, Russia

[3] JSC NIIneftepromchim, Kazan, Russia

[4] Ural Fed Univ, Inst Phys & Technol, Dept Rare Met & Nanomat, Ekaterinburg, Russia

[5] Kalashnikov Izhevsk State Tech Univ, Votkinsk Branch, Dept Technol Mech Engn & Instrument Making, Votkinsk, Russia

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 2022年 / 60卷 / 09期

关键词：

P-31 and Ag-109 NMR; N-thiophosphorylthiourea; polynuclear complexes; silver(I) complexes; solid-state NMR; CRYSTAL-STRUCTURES; SPECTROSCOPY; COPPER(I); CATION;

D O I：

10.1002/mrc.5294

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A family of three- and four-coordinated silver(I) complexes of formulas [Ag(PPh3)(2)L], [Ag(PPh3)L], and [AgL](n) with N-thiophosphorylated thiourea and thioamide ligands of general formula RC(S)NHP(S)(OPri)(2) [R = Ph, PhNH, iPrNH, tBuNH, NH2] have been studied by solid-state Ag-109 and P-31 CPMAS NMR spectroscopy. Ag-109 NMR spectra have provided valuable structural information about Ag coordination, which is in good accordance with the available crystal structure data. The data presented in this work represent a significant addition to the available Ag-109 chemical shifts and chemical shifts anisotropies. The silver chemical shift ranges for different P,S-environments and coordination state were discussed in detail. The (1)J(P-31-Ag-107/109) and (2)J(P-31-P-31) values were determined and analyzed.

引用

页码：893 / 900

页数：8

共 48 条

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