Photoelectrochemical study of the semiconductive properties of anodic oxide films on titanium-aluminum alloys

被引:0
|
作者
Kamkin, AN [1 ]
Davydov, AD
机构
[1] Moscow MV Lomonosov State Univ, Moscow 119899, Russia
[2] Russian Acad Sci, Frumkin Inst Electrochem, Moscow 117071, Russia
来源
PROTECTION OF METALS | 1999年 / 35卷 / 02期
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中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The properties (a band gap E-g and a flat band potential E-fb) of anodic oxide films, which were formed on several titanium-aluminum alloys (10-50 at. % Al) in solutions of various composition, are studied by photoelectrochemical method. It is found that E-g is virtually independent of alloy composition and only slightly depends on the solution composition. At an Increase in the pH value in a domain of 3 to 13, a linear decrease in E-fb is observed on pure titanium and on the alloy with 10 at. % Al; for the alloy with 50 at. % Al, the linearity is broken.
引用
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页码:134 / 138
页数:5
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