Third-order nonlinear optical response of newly synthesized accepter/donor substituted propylidene aryloxy acet hydrazide

被引:15
|
作者
Vijayakumar, S. [1 ]
Babu, M. [2 ]
Kalluraya, Balakrishna [2 ]
Chandrasekharan, K. [1 ]
机构
[1] Natl Inst Technol, Laser & Nonlinear Opt Lab, Dept Phys, Calicut 673601, Kerala, India
[2] Mangalore Univ, Dept Studies Chem, Mangalagangothri 574199, Karnataka, India
来源
OPTIK | 2012年 / 123卷 / 01期
关键词
Nonlinear absorption; Nonlinear refractive index; Synthesis; Z-scan; Optical limiting; Z-SCAN TECHNIQUE; SINGLE-BEAM; DERIVATIVES; ABSORPTION; CHROMOPHORES; COMPLEXES;
D O I
10.1016/j.ijleo.2010.09.051
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A class of organic compounds namely propylidene aryloxy acet hydrazide derivatives were synthesized. The third-order nonlinear optical properties and optical limiting studies of the compounds were investigated using the single beam Z-scan technique at 532 nm. The Z-scan study reveals that the compounds exhibit a self-defocusing effect at 532 nm. The calculated values of nonlinear refractive index, third-order nonlinear optical susceptibility and second order molecular hyperpolarizability are of the order of 10(-11) esu, 10(-13) esu and 10(-31) esu, respectively. The compounds exhibit good optical limiting properties at the wavelength used. (C) 2011 Elsevier GmbH. All rights reserved.
引用
收藏
页码:21 / 25
页数:5
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