Simultaneous spectroscopic and solid-state electronic measurement of single-walled carbon nanotube devices

被引:21
|
作者
Kauffman, Douglas R. [1 ,2 ]
Star, Alexander [1 ,2 ]
机构
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
[2] US DOE, Natl Energy TEchnol Lab, Pittsburgh, PA 15236 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 12期
关键词
D O I
10.1021/jp800166m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We describe simultaneous spectroscopic and solid-state electronic operation of a single-walled carbon nanotube (SWNT) thin film device under the influence of NH3 and NO2 gases. Using this simultaneous approach we show that both the optical absorbance and network conductance show a shared time dependency upon exposure to NH3 or NO2 gas. We show that the device behavior is dominated by gas adsorption on the SWNT network, and we explore the role of network density in regards to device behavior under gas exposure. Last, we provide evidence to suggest that the device sensitivity toward a particular analyte can be tuned by simply varying the density of the SWNT network.
引用
收藏
页码:4430 / 4434
页数:5
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