Highly fluorescent naphthalimide derivatives for two-photon absorption materials

被引：15
|
作者：
Li, J
Meng, FS
Tian, H [1 ]
Mi, J
Ji, W
机构：
[1] E China Univ Chem Technol, Lab Adv Mat, Shanghai 200237, Peoples R China
[2] E China Univ Chem Technol, Inst Fine Chem, Shanghai 200237, Peoples R China
[3] Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
来源：
CHEMISTRY LETTERS | 2005年 / 34卷 / 07期
关键词：
D O I：
10.1246/cl.2005.922
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel multi-branched naphthalimide derivatives (TPA-NA1, TPA-NA2, and TPA-NA3) were synthesized by the Sonogashira reaction of N-butyl-4-bromo-1,8-naphthalimide with mono-, di-, and tri-ethynylated triphenylamine. The fluorescence increases with the increase of branch number and the quantum yield is as high as 0.87 for TPA-NA3 in toluene. Two-photon absorption cross sections of TPA-NA3, TPA-NA2, and TPA-NA3 were determined to be 0.42 x 10(-20) cm(4)/ GW, 1.4 x 10-20 cm(4)/GW and 1.0 x 10(-20) cm(4) /GW (open aperture Z-scan, 120 fs, 780 nm), respectively.
引用
收藏
页码：922 / 923
页数：2
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