Phonon mode links ferroicities in multiferroic [(CH3)2NH2]Mn(HCOO)3

被引:16
|
作者
Hughey, Kendall D. [1 ]
Clune, Amanda J. [1 ]
Yokosuk, Michael O. [1 ]
al-Wahish, Amal [1 ]
O'Neal, Kenneth R. [1 ]
Fan, Shiyu [2 ]
Abhyankar, Nandita [3 ,4 ,5 ]
Xiang, Hongjun [6 ,7 ,8 ]
Li, Zhiqiang [4 ]
Singleton, John [9 ]
Dalal, Naresh S. [3 ,4 ]
Musfeldt, Janice L. [1 ,2 ]
机构
[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
[2] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA
[3] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA
[4] Natl High Magnet Field Lab, Tallahassee, FL 32310 USA
[5] NIST, Ctr Nanoscale Sci & Technol, Gaithersburg, MD 20878 USA
[6] Fudan Univ, State Key Lab Surface Phys, Minist Educ, Key Lab Computat Phys Sci, Shanghai 200433, Peoples R China
[7] Fudan Univ, Dept Phys, Shanghai 200433, Peoples R China
[8] Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[9] Los Alamos Natl Lab, Natl High Magnet Field Lab, Los Alamos, NM 87545 USA
基金
美国国家科学基金会;
关键词
METAL-ORGANIC FRAMEWORK; AUGMENTED-WAVE METHOD; WEAK FERROMAGNETISM; BEHAVIOR; FORMATE; TRANSITION; RAMAN;
D O I
10.1103/PhysRevB.96.180305
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We combined magnetoinfrared spectroscopy, magnetization, and lattice dynamics calculations to explore the phase transitions in multiferroic [(CH3)(2)NH2]Mn(HCOO)(3). Both the 185 K ferroelectric transition and the magnetically driven transition to the fully saturated state at 15.3 T involve the formate bending mode, direct evidence of a common connection between the two types of ferroicities and for how lattice distortions promote high-temperature magnetoelectric coupling in this system.
引用
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页数:5
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