Phonon mode links ferroicities in multiferroic [(CH3)2NH2]Mn(HCOO)3

被引：16

作者：

Hughey, Kendall D. ^{[1
]}

Clune, Amanda J. ^{[1
]}

Yokosuk, Michael O. ^{[1
]}

al-Wahish, Amal ^{[1
]}

O'Neal, Kenneth R. ^{[1
]}

Fan, Shiyu ^{[2
]}

Abhyankar, Nandita ^{[3
,4
,5
]}

Xiang, Hongjun ^{[6
,7
,8
]}

Li, Zhiqiang ^{[4
]}

Singleton, John ^{[9
]}

Dalal, Naresh S. ^{[3
,4
]}

Musfeldt, Janice L. ^{[1
,2
]}

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[2] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA

[3] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

[4] Natl High Magnet Field Lab, Tallahassee, FL 32310 USA

[5] NIST, Ctr Nanoscale Sci & Technol, Gaithersburg, MD 20878 USA

[6] Fudan Univ, State Key Lab Surface Phys, Minist Educ, Key Lab Computat Phys Sci, Shanghai 200433, Peoples R China

[7] Fudan Univ, Dept Phys, Shanghai 200433, Peoples R China

[8] Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China

[9] Los Alamos Natl Lab, Natl High Magnet Field Lab, Los Alamos, NM 87545 USA

来源：

PHYSICAL REVIEW B | 2017年 / 96卷 / 18期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORK; AUGMENTED-WAVE METHOD; WEAK FERROMAGNETISM; BEHAVIOR; FORMATE; TRANSITION; RAMAN;

D O I：

10.1103/PhysRevB.96.180305

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We combined magnetoinfrared spectroscopy, magnetization, and lattice dynamics calculations to explore the phase transitions in multiferroic [(CH3)(2)NH2]Mn(HCOO)(3). Both the 185 K ferroelectric transition and the magnetically driven transition to the fully saturated state at 15.3 T involve the formate bending mode, direct evidence of a common connection between the two types of ferroicities and for how lattice distortions promote high-temperature magnetoelectric coupling in this system.

引用

页数：5

共 50 条

[1] Magnetic field-temperature phase diagram of multiferroic [(CH3)2NH2]Mn(HCOO)3
Clune, A. J.
Hughey, K. D.
Lee, C.
Abhyankar, N.
Ding, X.
Dalal, N. S.
Whangbo, M. -H.
Singleton, J.
Musfeldt, J. L.
PHYSICAL REVIEW B, 2017, 96 (10)
[2] Magnetic transitions in metal-organic frameworks of [(CH3)2NH2] FeII(HCOO)3, [(CH3)2NH2]CoII(HCOO)3 and [(CH3)2NH2]FeIII FeII(HCOO)6
Zhou, Haitao
Pan, Desheng
Li, Yong
Li, Da
Choi, C. J.
Zhang, Zhidong
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2020, 493
[3] Developing the Pressure-Temperature-Magnetic Field Phase Diagram of Multiferroic [(CH3)2NH2]Mn(HCOO)3
Clune, Amanda
Harms, Nathan
O'Neal, Kenneth R.
Hughey, Kendall
Smith, Kevin A.
Obeysekera, Dimuthu
Haddock, John
Dalal, Naresh S.
Yang, Junjie
Liu, Zhenxian
Musfeldt, Janice L.
INORGANIC CHEMISTRY, 2020, 59 (14) : 10083 - 10090
[4] Structure-Property Relations in Multiferroic [(CH3)2NH2]M(HCOO)3 (M = Mn, Co, Ni)
Hughey, Kendall D.
Clune, Amanda J.
Yokosuk, Michael O.
Li, Jing
Abhyankar, Nandita
Ding, Xiaxin
Dalal, Naresh S.
Xiang, Hongjun
Smirnov, Dmitry
Singleton, John
Musfeldt, Janice L.
INORGANIC CHEMISTRY, 2018, 57 (18) : 11569 - 11577
[5] First-order structural transition in the multiferroic perovskite-like formate [(CH3)2NH2][Mn(HCOO)3]
Sanchez-Andujar, M.
Gomez-Aguirre, L. C.
Doldan, B. Pato
Yanez-Vilar, S.
Artiaga, R.
Llamas-Saiz, A. L.
Manna, R. S.
Schnelle, F.
Lang, M.
Ritter, F.
Haghighirad, A. A.
Senaris-Rodriguez, M. A.
CRYSTENGCOMM, 2014, 16 (17): : 3558 - 3566
[6] Magnetic and electric characterization of multiferroic organometallic compound [(CH3)2NH2]Mn0.5Ni0.5(HCOO)3
Chakraborty, Tirthankar
Elizabeth, Suja
SOLID STATE COMMUNICATIONS, 2017, 261 : 1 - 5
[7] Raman scattering studies of pressure-induced phase transitions in perovskite formates [(CH3)2NH2][Mg(HCOO)3] and [(CH3)2NH2][Cd(HCOO)3]
Maczka, M.
Almeida da Silva, T.
Paraguassu, W.
Pereira da Silva, K.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2016, 156 : 112 - 117
[8] Temperature dependent negative differential resistance behavior in multiferroic metal organic framework (CH3)2NH2 Mn (HCOO)3 crystals
Malik, Vikas
Maity, Sarmistha
Chatterjee, Ratnamala
ORGANIC ELECTRONICS, 2018, 56 : 5 - 10
[9] Strain coupling and dynamic relaxation in multiferroic metal-organic framework [(CH3)2NH2] [Mn(HCOO)3] with perovskite structure
Zhang, Zhiying
Tang, Hao
Cheng, Dongpeng
Zhang, Jikang
Chen, Yatao
Shen, Xin
Yu, Hongliang
RESULTS IN PHYSICS, 2019, 12 : 2183 - 2188
[10] Structural, magnetic and phonon properties of Cr(III)-doped perovskite metal formate framework [(CH3)2NH2][Mn(HCOO)3]
Maczka, Miroslaw
Gagor, Anna
Hermanowicz, Krzysztof
Sieradzki, Adam
Macalik, Lucyna
Pikul, Adam
JOURNAL OF SOLID STATE CHEMISTRY, 2016, 237 : 150 - 158

← 1 2 3 4 5 →