Synthesis, characterization and catalytic activity of dinuclear iron(III) and ruthenium(III) complexes

被引：21
|
作者：
Aneetha, H [1 ]
Padmaja, J [1 ]
Zacharias, PS [1 ]
机构：
[1] UNIV HYDERABAD, SCH CHEM, HYDERABAD 500046, ANDHRA PRADESH, INDIA
来源：
POLYHEDRON | 1996年 / 15卷 / 14期
关键词：
D O I：
10.1016/0277-5387(95)00503-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A number of dinuclear iron(III) and ruthenium(III) complexes from dinucleating ligands have been synthesised and characterized. The iron(III) complexes of dinucleating triazene-1-oxide ligands (type 1) catalyse the epoxidation of alkenes with iodosyl benzene as an oxidant. The catalytic activity of iron(III) complexes of dinucleating Schiff base ligands (type 2) could not be studied due to insolubility. Ruthenium(III) complexes of both types of ligands catalyse epoxidation reactions. Copyright (C) 1996 Elsevier Science Ltd.
引用
收藏
页码：2445 / 2451
页数：7
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