Preparation and structure of [Ru(CO)2(PPh3)(η-C5Me5)][Fe3(μ3-C2But)(CO)9]

被引:6
|
作者
Bruce, MI [1 ]
Zaitseva, NN
Skelton, BW
White, AH
机构
[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia
[2] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia
关键词
D O I
10.1071/C98004
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction between RuCl(C=CHBut)(PPh3)(eta-C5Me5) and Fe-2(CO)(9) afforded the salt [Ru(CO)(2)(PPh3)(eta-C5Me5)][Fe-3(mu(3)-C2But)(CO)(9)], which has been characterized by a single-crystal X-ray structure determination. The cation has a piano-stool structure, while the anion contains a CCBut ligand sitting on a triangular Fe-3 cluster.
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页码:433 / 435
页数:3
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