A green method of adipic acid synthesis: organic solvent- and halide-free oxidation of cycloalkanones with 30% hydrogen peroxide

被引：104
|
作者：
Usui, Y [1 ]
Sato, K [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba Cent 5, Tsukuba, Ibaraki 3058565, Japan
来源：
GREEN CHEMISTRY | 2003年 / 5卷 / 04期
关键词：
D O I：
10.1039/b305847f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cyclohexanone and cyclohexanol are oxidized to adipic acid in high yield with aqueous 30% H2O2 in the presence of H2WO4 as a catalyst under organic solvent- and halide-free conditions. It is important that no solvent is used in order to achieve high reactivity in this heterogeneous reaction. The use of t-butyl alcohol or dioxane as a solvent (homogeneous conditions) significantly decreases the yield of adipic acid from cyclohexanone. This ketone-to-dicarboxylic acid conversion is applicable to five- to eight-membered cyclic ketones. No operational problems are foreseen for a large-scale version of this green process.
引用
收藏
页码：373 / 375
页数：3
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