(Croconato-κ2O,O′)bis(1,10-phenanthro line κ2 N,N′ )manganese(II)

被引：4

作者：

Chen, Hong-Feng ^{[1
]}

Chen, Hong-Yu ^{[2
]}

Chen, Xia ^{[1
]}

Batsanov, Andrei S. ^{[3
]}

Fang, Qi ^{[1
]}

机构：

[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

[2] Taishan Med Univ, Fac Chem & Chem Engn, Tai An 271000, Peoples R China

[3] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536807065841

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Mn(C5O5)(C12H8N2)(2)], lies across a crystallographic twofold axis which passes through the Mn atom and bisects the croconate ligand. The two 1,10-phenanthroline (phen) ligands are arranged in a propeller manner and the local molecular geometry of the MnN4O2 unit is severely distorted octahedral. This may be interpreted as a structural perturbation of the MnN4 square by the croconate ligand. In the crystal structure, the dipole moments of the molecules are arranged alternately along the +b and -b directions. All the phen ligands are involved in pi stacking interactions, alternately along the [110] and [110] directions. The alternate spacings between the neighbouring phen planes in the one-dimensional pi stacks are 3.361 (2) and 3.526 (2) angstrom.

引用

页码：M172 / U1639

页数：10

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