3d-transition metal catalyzed C-H to C-N bond formation: An update

被引：17

作者：

Singh, Ritesh ^{[1
]}

Sathish, Elagandhula ^{[1
]}

Gupta, Ashis K. ^{[1
]}

Goyal, Sophiya ^{[1
]}

机构：

[1] Cent Univ Rajasthan, Sch Chem Sci & Pharm, NH-8, Ajmer 305817, Rajasthan, India

来源：

TETRAHEDRON | 2021年 / 100卷

关键词：

C-H functionalization; C-N bond formation; Sustainable catalysis; Earth abundant catalyst; CARBON-NITROGEN BONDS; C(SP(3))-H AMINATION; SELECTIVE AMIDATION; ARENES; COBALT(III); DERIVATIVES; MILD; ARYL; ACTIVATION; STRATEGY;

D O I：

10.1016/j.tet.2021.132474

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct C-H bond amination is an emerging area of research among synthetic community owing to prevalence of N-bearing scaffolds in various fields of importance to humankind. In this direction, use of 3d transition metals (Cu, Co, Ni and Fe) have recently emerged as promising class of catalytic promoters for C-H to C-N bond formation through different mechanistic manifolds in order to make the transformation more sustainable and industrially oriented. Herein, we provide an update on 3d-transition metal mediated C-H bond amination reactions showcasing the recent developments in this area, thus clearly outlining the scope and limitations of the developed methods and illustrating the focus area to be addressed in the near future. (C) 2021 Elsevier Ltd. All rights reserved.

引用

页数：56

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