Scalable synthesis of hydroxymethyl alkylfuranoates as stable 2,5-furandicarboxylic acid precursors

被引：1

作者：

Pedersen, Martin Jaeger ^{[1
]}

Jurys, Arminas ^{[1
]}

Pedersen, Christian Marcus ^{[1
]}

机构：

[1] Univ Parken 5, Copenhagen 2100 O, Denmark

来源：

GREEN CHEMISTRY | 2020年 / 22卷 / 08期

关键词：

AEROBIC OXIDATION; CONVERSION; BIOMASS; PLATFORM; CHEMICALS; HUMINS;

D O I：

10.1039/d0gc00770f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroxymethyl furanoic acid and its derivatives have been synthesized in high yields and purity from gluconolactone. The reaction sequence allows the recovery of reagents and the use of bio-friendly chemicals and solvents, and can easily be scaled up. The reaction product on a >100 gram scale can be purified by a single purification method, such as distillation or precipitation. The overall yield is above 50%.

引用

页码：2399 / 2402

页数：4

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