A Facile and Efficient Synthesis of 2-Imidazolines from Aldehydes Using Hydrogen Peroxide and Substoichiometric Sodium Iodide

被引:24
|
作者
Bai, Guo-yi [1 ]
Xu, Kai [1 ]
Chen, Guo-feng [1 ]
Yang, Yong-hui [1 ]
Li, Tian-yu [1 ]
机构
[1] Hebei Univ, Key Lab Chem Biol Hebei Prov, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
来源
SYNTHESIS-STUTTGART | 2011年 / 10期
基金
中国国家自然科学基金;
关键词
2-imidazoline; hydrogen peroxide; aldehydes; ethylenediamine; environmentally friendly process; ONE-POT SYNTHESIS; IMIDAZOLINES; NITRILES; LIGAND;
D O I
10.1055/s-0030-1259992
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of aldehydes with ethylenediamine for the preparation of 2-imidazolines has been studied using hydrogen peroxide as an oxidant in the presence of sodium iodide and anhydrous magnesium sulfate. A mild, green, and efficient method is established to carry out this reaction in high yield.
引用
收藏
页码:1599 / 1603
页数:5
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