The stereochemistry of epoxidation of Δ5-steroids with sodium perborate and potassium permanganate

被引：14
|
作者：
Hanson, JR [1 ]
Terry, N [1 ]
Uyanik, C [1 ]
机构：
[1] Univ Sussex, Sch Mol Sci, Brighton BN1 9QJ, E Sussex, England
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 1998年 / 01期
关键词：
D O I：
10.1039/a706111k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Sodium perborate, with potassium permanganate as a catalyst, has been shown to be a novel reagent for the epoxidation of steroidal 5-enes with the attack occurring predominantly on the beta-face.
引用
收藏
页码：50 / 51
页数：3
相关论文
共 50 条
  • [41] ON STEROIDS .283. STEREOCHEMISTRY OF EPOXIDATION AND HYDROBORATION OF SOME 4,4-DIMETHYL-A-HOMO-5-CHOLESTENE DERIVATIVES
    VELGOVA, H
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1983, 48 (06) : 1774 - 1782
  • [42] STEREOCHEMISTRY OF EPOXIDATION OF SOME A-NORANDROST-5-ENES
    GORDON, JF
    HANSON, JR
    HITCHCOCK, PB
    JARVIS, AG
    WADSWORTH, HJ
    RATCLIFFE, AH
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (06): : 1473 - 1475
  • [43] POTASSIUM PERMANGANATE AS AN ABORTIFACIENT - A 5 YEAR REVIEW
    CABANISS, CM
    CLARK, JFJ
    AMERICAN JOURNAL OF OBSTETRICS AND GYNECOLOGY, 1962, 83 (01) : 13 - &
  • [44] Mild and regioselective oxidative bromination of anilines using potassium bromide and sodium perborate
    Roche, D
    Prasad, K
    Repic, O
    Blacklock, TJ
    TETRAHEDRON LETTERS, 2000, 41 (13) : 2083 - 2085
  • [45] The effect of 4β and 19 ester functionalities on some electrophilic addition reactions of Δ5-steroids
    Ruddock, PLD
    Reese, PB
    STEROIDS, 1999, 64 (12) : 812 - 819
  • [46] Direct Cu-Catalyzed Allylic Acetoxylation of Δ5-Steroids at 7-Position
    Rahman, Faiz Ur
    Rahman, Ata Ur
    Tan, Tian-Wei
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2010, 57 (6B) : 1237 - 1242
  • [47] Study on Partially Oxidized Sodium Alginate with Potassium Permanganate as the Oxidant
    Lu, Lingbin
    Zhang, Ping
    Cao, Yang
    Lin, Qiang
    Pang, Sujuan
    Wang, Huaming
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 113 (06) : 3585 - 3589
  • [48] Quantitative and Stereospecific Dihydroxylations of Δ5-Steroids: A Green Synthesis of Plant Growth Hormone Intermediates
    Li, Tao
    Li, Chunbao
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2013, 61 (51) : 12522 - 12530
  • [49] An Effective Method for Allylic Oxidation of Δ5-Steroids Using tert-Butyl Hydroperoxide
    Li, Yuancheng
    Wu, Xianhong
    Lee, Tae Bum
    Isbell, Eleanor K.
    Parish, Edward J.
    Gorden, Anne E. V.
    JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (05): : 1807 - 1810
  • [50] HYDROPEROXIDE REACTIONS .18. STEREOCHEMISTRY OF CATALYZED EPOXIDATION OF STEROIDS BY TERT AMYL HYDROPEROXIDE
    TOLSTIKOV, GA
    YUREV, VP
    GAILYUNA.IA
    DZHEMILE.UM
    ZHURNAL OBSHCHEI KHIMII, 1974, 44 (01): : 215 - 220
12345