Synthesis and X-ray crystal structures of novel Al-Bi and Ga-Bi compounds

被引：35
|
作者：
Kuczkowski, A [1 ]
Thomas, F [1 ]
Schulz, S [1 ]
Nieger, M [1 ]
机构：
[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany
来源：
ORGANOMETALLICS | 2000年 / 19卷 / 26期
关键词：
D O I：
10.1021/om0007365
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions between trialkylgallanes GaR3 (R = Me, Et, t-Bu) and triorganobismuthanes BiR'(3) (R' = i-Pr, SiMe3) lead to the formation of six Lewis acid-base adducts of the type R3Ga . BiR'3 (Me3Ga . Bi(SiMe3)(3), 1, Et3Ga . Bi(SiMe3)(3), 2, t-Bu3Ga . Bi(SiMe3)(3), 3, Me3Ga . Bi(i-Pr)(3), 4, Et3Ga . Bi(i-Pr)(3), 5, t-Bu3Ga . Bi(i-Pr)(3), 6). 2 and 6 are the first structurally characterized main group element-triorganobismuthane Lewis acid-base adducts. In addition, the synthesis and structural characterization of two Lewis base-stabilized,monomeric aluminum bismuthides of the type base-Al(R-2)Bi(SiMe3)(2) (base =; 4-(dimethylamino)pyridine (dmap); R = Me 7, Et 8) is reported.
引用
收藏
页码：5758 / 5762
页数：5
相关论文
共 50 条
  • [21] X-ray studies on Bi single crystals
    Goetz, A
    Hergenrother, RC
    PHYSICAL REVIEW, 1932, 40 (02): : 137 - 150
  • [22] Synthesis and X-ray Crystal Structures of Tetranuclear Zincamidinate Complexes
    Gutschank, Benjamin
    Schulz, Stephan
    Westphal, Ulrich
    Blaeser, Dieter
    Boese, Roland
    ORGANOMETALLICS, 2010, 29 (09) : 2093 - 2097
  • [23] Synthesis and X-ray crystal structures of some isothiosemicarbazone complexes
    Takjoo, R.
    Moghadam, S. M. Mashmoul
    Rudbari, H. Amiri
    Bruno, G.
    TRANSITION METAL CHEMISTRY, 2019, 44 (06) : 525 - 534
  • [24] Synthesis and X-ray crystal structures of some isothiosemicarbazone complexes
    R. Takjoo
    S. M. Mashmoul Moghadam
    H. Amiri Rudbari
    G. Bruno
    Transition Metal Chemistry, 2019, 44 : 525 - 534
  • [25] ARYL COMPOUNDS OF RHODIUM - SYNTHESES AND X-RAY CRYSTAL-STRUCTURES
    HAYMOTHERWELL, RS
    KOSCHMIEDER, SU
    WILKINSON, G
    HUSSAINBATES, B
    HURSTHOUSE, MB
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (11): : 2821 - 2830
  • [26] Synthesis and X-ray crystal structures of novel spiro 1,3-benzoxazine dimers
    Alkhathlan, HZ
    Al-Saad, MA
    Al-Hazimi, HM
    Al-Farhan, KA
    Mousa, AA
    JOURNAL OF CHEMICAL RESEARCH, 2002, (10) : 473 - 474
  • [27] Real-time Observation on Coarsening of Second-Phase Droplets in Al-Bi Immiscible Alloy Using Synchrotron Radiation X-ray Imaging Technology
    Kang, Hui-Jun
    Zhou, Peng
    Cao, Fei
    Zhu, Jing
    Fu, Ya-Nan
    Huang, Wan-Xia
    Xiao, Ti-Qiao
    Wang, Tong-Min
    ACTA METALLURGICA SINICA-ENGLISH LETTERS, 2015, 28 (07) : 940 - 945
  • [28] Synthesis and x-ray characterization of sputtered bi-alkali antimonide photocathodes
    Gaowei, M.
    Ding, Z.
    Schubert, S.
    Bhandari, H. B.
    Sinsheimer, J.
    Kuehn, J.
    Nagarkar, V. V.
    Marshall, M. S. J.
    Walsh, J.
    Muller, E. M.
    Attenkofer, K.
    Frisch, H. J.
    Padmore, H.
    Smedley, J.
    APL MATERIALS, 2017, 5 (11):
  • [29] X-ray photoelectron spectroscopies of Ni-doped Bi-2212 compounds
    Man, NK
    Garg, KB
    Hien, TD
    Sinh, NH
    Phuc, NX
    Venkatesh, S
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1998, 177 : 527 - 528
  • [30] X-RAY ANALYSIS OF CRYSTAL STRUCTURES
    HARDING, MM
    CHEMISTRY IN BRITAIN, 1968, 4 (12) : 548 - &
12345