1,3,4,6-Tetrachloroglycoluril (TCGV) mediated isothiocyanation of phosphites, phosphonites and phosphinites

被引：0
|
作者：
Guo, Huichuang [1 ]
Li, Junchen [1 ]
Zhang, Yulong [1 ]
Mao, Tengfei [1 ]
Gao, Runli [1 ]
Guo, Yongbiao [1 ]
Shi, Enxue [1 ]
机构：
[1] State Key Lab NBC Protect Civilian, State Key Lab NBC Protect, Beijing, Peoples R China
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2022年 / 197卷 / 11期
关键词：
Isothiocyanation; 1; 3; 4; 6-tetrachloroglycoluril; phosphoroisothiocyanates; phosphonoisothiocyanates; phosphinoisothiocyanates; PSEUDOHALOGENATION;
D O I：
10.1080/10426507.2022.2065491
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A universal and facile isothiocyanation protocol of P(O)H functionality with inorganic thiocyanides mediated by 30% equimolar 1,3,4,6-tetrachloroglycoluril (TCGV) was developed for the preparation of the corresponding phosphoroisothiocyanates, phosphonoisothiocyanates and phosphinoisothiocyanates. P(O)Cl was found to be the intermediate in situ formed in the reaction.
引用
收藏
页码：1157 / 1159
页数：3
相关论文
共 50 条
  • [21] REDUCTIVE DIMERIZATION OF 1,3,4,6-TETRAMETHYL-2-PHENYLPYRIMIDINIUM BISTETRAFLUOBORATE
    DOUGLASS, JE
    BUMGARNER, DL
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1981, 18 (02) : 417 - 418
  • [22] 1,3,4,6-tetracarbonyl systems. Part 8. Synthesis and antimicrobial activity of 2(5)-halogenated derivatives of 1,3,4,6-tetracarbonyl compounds
    Kozminykh E.N.
    Goncharov V.I.
    Kozminykh V.O.
    [J]. Pharmaceutical Chemistry Journal, 2008, 42 (9) : 513 - 519
  • [23] ELECTROCHEMICAL SYNTHESIS OF 1,3,4,6-TETRATHIAPENTALENE-2,5-DITHIONE
    KRUG, WP
    BLOCH, AN
    COWAN, DO
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (18) : 660 - 660
  • [24] Synthesis of 1,3,4,6-Tetra-O-acetyl-l-gulose
    Che, Rui
    Liu, Xingui
    Lu, Wei
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2017, 35 (02) : 237 - 241
  • [25] Reaction of 1,3,4,6-tetraketones with p-toluidine and benzaldehyde
    P. P. Mukovoz
    V. O. Koz’minykh
    A. V. Gorbunova
    E. N. Koz’minykh
    P. A. Slepukhin
    I. N. Ganebnykh
    O. S. El’tsov
    [J]. Russian Journal of Organic Chemistry, 2016, 52 : 838 - 843
  • [26] Reaction of 1,3,4,6-tetraketones with p-toluidine and benzaldehyde
    Mukovoz, P. P.
    Koz'minykh, V. O.
    Gorbunova, A. V.
    Koz'minykh, E. N.
    Slepukhin, P. A.
    Ganebnykh, I. N.
    El'tsov, O. S.
    [J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 52 (06) : 838 - 843
  • [27] Hydroxyoligophosphites and -phosphonites on the basis of 1,4:3,6-dianhydro-D-sorbitol
    Bratash, GS
    Grachev, MK
    Kurochkina, GI
    Vasyanina, LK
    Nifantiev, EE
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2005, 180 (11) : 2593 - 2599
  • [28] SYNTHESIS OF THE 1ST EXAMPLE OF A 1,3,4,6-TETRAPHOSPHA-HEXATRIENE COMPLEX
    DELPOZO, AG
    CAMINADE, AM
    DAHAN, F
    MAJORAL, JP
    MATHIEU, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (09) : 574 - 575
  • [29] SYNTHESIS OF 1,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOPYRANOSE AND 1,3,4,6-TETRA-O-ACETYL-BETA-D-GALACTOPYRANOSE AND THEIR ALPHA-GLYCOSYLBROMIDE DERIVATIVES
    CHARI, VM
    JORDAN, M
    WAGNER, H
    [J]. ACTA CHIMICA ACADEMIAE SCIENTARIUM HUNGARICAE, 1977, 93 (01): : 99 - 102
  • [30] A SIMPLIFIED SYNTHESIS OF ALPHA-D-GALACTOPYRANOSE 1,3,4,6-TETRAACETATE
    CHITTENDEN, GJF
    [J]. CARBOHYDRATE RESEARCH, 1988, 183 (01) : 140 - 143
12345