1,3,4,6-Tetrachloroglycoluril (TCGV) mediated isothiocyanation of phosphites, phosphonites and phosphinites

被引：0
|
作者：
Guo, Huichuang [1 ]
Li, Junchen [1 ]
Zhang, Yulong [1 ]
Mao, Tengfei [1 ]
Gao, Runli [1 ]
Guo, Yongbiao [1 ]
Shi, Enxue [1 ]
机构：
[1] State Key Lab NBC Protect Civilian, State Key Lab NBC Protect, Beijing, Peoples R China
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2022年 / 197卷 / 11期
关键词：
Isothiocyanation; 1; 3; 4; 6-tetrachloroglycoluril; phosphoroisothiocyanates; phosphonoisothiocyanates; phosphinoisothiocyanates; PSEUDOHALOGENATION;
D O I：
10.1080/10426507.2022.2065491
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A universal and facile isothiocyanation protocol of P(O)H functionality with inorganic thiocyanides mediated by 30% equimolar 1,3,4,6-tetrachloroglycoluril (TCGV) was developed for the preparation of the corresponding phosphoroisothiocyanates, phosphonoisothiocyanates and phosphinoisothiocyanates. P(O)Cl was found to be the intermediate in situ formed in the reaction.
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页码：1157 / 1159
页数：3
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