Synthesis and crystal structure of a dinuclear Cu(II) complex with tridentate Schiff base and azido bridge

被引：0
|
作者：
Lin, H
Feng, YL [1 ]
Gao, S
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China
[2] Jinhua Profess Tech Coll, Jinhua 321017, Peoples R China
[3] Heilongjiang Univ, Coll Chem & Chem Engn, Harbin 150080, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2005年 / 24卷 / 04期
关键词：
3-dimethylamino-1-propylamine; salicylaldehyde; Schiff base; Cu(II) complex; crystal structure; bridging azide;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new dinuclear copper(H) complex ([Cu(C12H17N2O)(N-3)](2), C24H34Cu2O2) has been synthesized and characterized by X-ray structure determination. It crystallizes in the monoclinic system, space group P2(1)/c with a = 18.529(4), b = 10.933(), c = 14.534(3) angstrom, beta = 111.07(3)degrees, V = 2748(1) angstrom(3), Z = 4, M-r = 621.69, F(OOO) = 1288, D-c= 1.503 g/cm(3) and mu(MoK alpha) = 1.590 mm(-1). The structure was refined to R = 0.0647 and wR = 0. 1846 for 4406 observed reflections (1 > 2 sigma (I)). The asymmetric unit comprises two halfmolecules. The complex is a centrosymmetric dimmer in which the copper atoms are penta-coordinated by three coordination atoms from the corresponding tridentate Schiff base ligand and two bridging azide anions. The Cu(II)... Cu(II) average distance is 3.350(1) angstrom.
引用
收藏
页码：375 / 378
页数：4
相关论文
共 50 条
  • [21] In Situ Synthesis, Characterization and Crystal Structure of a Novel Cobalt(III) Complex with Tridentate Schiff Base
    Zhang, Chen-Xi
    Cui, Chunxian
    Lu, Ming
    Yu, Liang
    Zhan, Yue-Xiong
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (03) : 136 - 138
  • [22] Synthesis and crystal structure of mononuclear copper(II) complex of tridentate Schiff base ligand and its ferrocyanide-bridged pentanuclear complex
    Mondal, N
    Saha, MK
    Bag, B
    Mitra, S
    Rosair, G
    El Fallah, MS
    POLYHEDRON, 2001, 20 (7-8) : 579 - 584
  • [23] Synthesis, Crystal Structure, and Cytotoxic Activity of a Novel Eight-Coordinated Dinuclear Ca(II)-Schiff Base Complex
    Tai, Xi-Shi
    Meng, Qing-Guo
    Liu, Li-Li
    CRYSTALS, 2016, 6 (09):
  • [24] Synthesis and crystal structure of a novel binuclear Cu(II) complex with tetradentate Schiff-base ligand
    Zhao Hai-Yan
    Qiu Xiao-Hang
    Tong Xiao-Lan
    Shen Pan-Wen
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (09) : 1095 - 1099
  • [25] Synthesis and Crystal Structure of a Novel Dinuclear Copper(Ⅱ) Complex Containing Benzimidazole Schiff Base Ligand
    刘家成
    陈立伟
    宋雪艳
    洪慧琴
    楚朝霞
    结构化学, 2011, 30 (05) : 764 - 767
  • [26] Synthesis, Crystal Structure, and Magnetic Properties of a New Dinuclear Iron Complex with Schiff Base Ligand
    曹洪玉
    结构化学, 2015, 34 (03) : 441 - 446
  • [27] Synthesis, Crystal Structure, and Magnetic Properties of a New Dinuclear Iron Complex with Schiff Base Ligand
    Cao Hong-Yu
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (03) : 441 - 446
  • [28] Synthesis, structure and electrochemistry of dinuclear copper(II) complex with dinucleating Schiff-base ligand
    Zhang, WX
    Liu, SY
    Ma, CQ
    Jiang, DH
    POLYHEDRON, 1998, 17 (22) : 3835 - 3839
  • [29] Synthesis and crystal structure of a dinuclear Cu(II) complex [CU(C12H17N2O)(NCS)]2 with tridentate Schiff base ligand N-(salicylidene)-3-dimethylaminopropylamine
    Lin, H
    Feng, YL
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (03) : 346 - 348
  • [30] Synthesis, structure, protein binding of Cu(II) complexes with a tridentate NNO Schiff-base ligand
    Li, Mei
    Huang, ShuJuan
    Ye, Cheng
    Xie, YongRong
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 150 : 290 - 300
12345