Supramolecular self-assembly and selective step decoration on the Au(111) surface

被引:46
|
作者
Vladimirova, M [1 ]
Stengel, M
De Vita, A
Baldereschi, A
Böhringer, M
Morgenstern, K
Berndt, R
Schneider, WD
机构
[1] Inst Romand Rech Numer Phys Mat, PPH Ecublens, CH-1015 Lausanne, Switzerland
[2] Univ Trieste, INFM, I-34127 Trieste, Italy
[3] Univ Trieste, Dipartimento Ingn Mat, I-34127 Trieste, Italy
[4] Univ Lausanne, Inst Phys Mat Condensee, CH-1015 Lausanne, Switzerland
[5] Univ Kiel, Inst Expt & Angew Phys, D-24098 Kiel, Germany
来源
EUROPHYSICS LETTERS | 2001年 / 56卷 / 02期
关键词
D O I
10.1209/epl/i2001-00514-3
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Scanning tunneling microscopy of low coverages of 1-nitronaphtalene ( NN) on reconstructed Au( 111) reveals that the face-centered-cubic ( fcc) reconstruction domains of steps are densely and selectively decorated. Molecular dynamics simulations identify this phenomenon as the self-assembly of hydrogen-like bonded supramolecular chains driven by the step electrostatic potential. First principles calculations predict weak adsorption at domain boundaries, and stable adsorption at the step edge of the fcc domains, explaining the selective decoration.
引用
收藏
页码:254 / 260
页数:7
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