Modulation of electrical properties in single-walled carbon nanotube/conducting polymer composites

The preparation and electrical characterization of a new class of composite layers formed by dispersing single-walled carbon nanotubes (SWNTT) in 1,8-diaminonaphthalene polymer, the poly(1,8-DAN), are described. The material was grown oil the surface of Pt plates by electropolymerization of 1,8-diaminonaphthalene (1,8-DAN) monomer in the presence of nanotubes. This synthesis method allows the simultaneous deposition of both the host polymer matrix and the filler nanotubes. A series of composite films were prepared using untreated nanotubes as well as nanotubes treated with KOH, HNO3 and HNO3/H2SO4 solutions. The structural features of the nanotubes and of the films produced have been investigated using Raman spectroscopy. Insight into the nature of nanotube dispersion and nanotube-polymer association was gained by AFM and STM analysis and by FE-SEM inspection after removing the outermost portion of composite films. The charge transport in composite films is found to be strongly enhanced by the nanotube insertion. Depending on the SWNTs processing, currents LIP to 30 mA, higher by a factor of about 140 than those of the pure poly(1,8-DAN) films, were measured with an applied voltage of 250 mV. (c) 2005 Elsevier Ltd. All rights reserved.