Oxidative dehydrogenation of ethane to ethene over a superbase supported LiCl system

被引：8
|
作者：
Zhao, Yu Bao [1 ]
Tan, Wen Wen [1 ]
Li, Hui [1 ]
Jia, Xiao Hui [1 ]
Wan, Hui Lin [2 ,3 ]
机构：
[1] Univ S China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China
[2] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
[3] Xiamen Univ, Inst Phys Chem, Xiamen 361005, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2010年 / 21卷 / 11期
关键词：
Oxidative dehydrogenation; ODH; Ethane; Ethene; Superbase; LiCl; SELECTIVE OXIDATION; CATALYSTS; PERFORMANCE; ETHYLENE; PROPANE; ALKANES; EPR;
D O I：
10.1016/j.cclet.2010.06.025
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
LiCl-promoted superbase catalysts were found to be stable and highly selective to ethene for oxidative dehydrogenation of ethane, giving 84% ethane conversion and 74% ethene yield at 923 K. Results indicated that the stronger the basicity of LiCl-based catalysts, the better the catalytic performance. (C) 2010 Yu Bao Zhao. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：1366 / 1369
页数：4
相关论文
共 50 条
  • [41] Highly Selective Supported Alkali Chloride Catalysts for the Oxidative Dehydrogenation of Ethane
    Christian A. Gärtner
    Andre C. van Veen
    Johannes A. Lercher
    [J]. Topics in Catalysis, 2014, 57 : 1236 - 1247
  • [42] Kinetics and mechanism of oxidative dehydrogenation of ethane and propane on supported vanadium oxide
    Argyle, MD
    Chen, KD
    Bell, AT
    Iglesia, E
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U22 - U22
  • [43] Oxidative Dehydrogenation of Ethane to Ethylene over Potassium Tungstate Catalysts
    Li, Duanxing
    Wei, Zenghao
    Takanabe, Kazuhiro
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2024, 63 (13) : 5646 - 5654
  • [44] Oxidative dehydrogenation of ethane over Pt-Sn catalysts
    Silberova, B
    Holm, J
    Holmen, A
    [J]. NATURAL GAS CONVERSION VII, 2004, 147 : 685 - 690
  • [45] Oxidative dehydrogenation of ethane over boron-containing chabazite
    Kuo, Mi Jen
    Huang, Xinlei
    Bai, Shi
    Vlachos, Dionisios G.
    Lobo, Raul F.
    [J]. APPLIED CATALYSIS A-GENERAL, 2024, 680
  • [46] Oxidative dehydrogenation of ethane over iron phosphate catalysts.
    Miller, JE
    Gonzales, MM
    Evans, L
    Saint, AG
    Zhang, C
    Whitwell, G
    Maiti, A
    King-Smith, D
    Kung, P
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U318 - U318
  • [47] Direct Insight into Ethane Oxidative Dehydrogenation over Boron Nitrides
    Huang, Rui
    Zhang, Bingsen
    Wang, Jia
    Wu, Kuang-Hsu
    Shi, Wen
    Zhang, Yajie
    Liu, Yuefeng
    Zheng, Anmin
    Schloegl, Robert
    Su, Dang Sheng
    [J]. CHEMCATCHEM, 2017, 9 (17) : 3293 - 3297
  • [48] Halide promoted catalysts with defective fluorite structure for selective oxidative dehydrogenation of ethane to ethene.
    Wan, HL
    Weng, WZ
    Chen, MS
    Zhu, YM
    Chen, T
    Tsai, KR
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U641 - U641
  • [49] Excellent promotion by lithium of a lanthanum-calcium oxide catalyst for oxidative dehydrogenation of ethane to ethene
    Ji, L
    Liu, JS
    [J]. CHEMICAL COMMUNICATIONS, 1996, (10) : 1203 - 1203
  • [50] Study on oxidative cracking of ethane to ethene
    [J]. 2000, Beijing Research Institute of Chemical Industry, China (29):
12345