Oxidative dehydrogenation of ethane to ethene over a superbase supported LiCl system

被引:8
|
作者
Zhao, Yu Bao [1 ]
Tan, Wen Wen [1 ]
Li, Hui [1 ]
Jia, Xiao Hui [1 ]
Wan, Hui Lin [2 ,3 ]
机构
[1] Univ S China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China
[2] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
[3] Xiamen Univ, Inst Phys Chem, Xiamen 361005, Peoples R China
关键词
Oxidative dehydrogenation; ODH; Ethane; Ethene; Superbase; LiCl; SELECTIVE OXIDATION; CATALYSTS; PERFORMANCE; ETHYLENE; PROPANE; ALKANES; EPR;
D O I
10.1016/j.cclet.2010.06.025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
LiCl-promoted superbase catalysts were found to be stable and highly selective to ethene for oxidative dehydrogenation of ethane, giving 84% ethane conversion and 74% ethene yield at 923 K. Results indicated that the stronger the basicity of LiCl-based catalysts, the better the catalytic performance. (C) 2010 Yu Bao Zhao. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码:1366 / 1369
页数:4
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