Structure of Fe3O complexes with long alkyl chain fatty acid, [Fe3O(O2CCnH2n+1)6L3]NO3 (L = H2O, n = 11, 13, 15, 17; L = py, n = 13, 15, 17);: crystal structure of [Fe3O(O2CC13H27)6(py)3]NO3

被引：16

作者：

Nakamoto, T ^{[1
]}

Katada, M

Endo, K

Sano, H

机构：

[1] Japan Atom Energy Res Inst, Adv Sci Res Ctr, Tokai, Ibaraki 3191195, Japan

[2] Tokyo Metropolitan Univ, Radioisotope Res Ctr, Tokyo 1920397, Japan

[3] Showa Coll Pharmaceut Sci, Tokyo 1948543, Japan

[4] Otsuma Womens Univ, Sch Social Informat Studies, Dept Environm Sci, Tokyo 2068540, Japan

来源：

POLYHEDRON | 1998年 / 17卷 / 20期

关键词：

trinuclear iron complex; long alkyl chain carboxylate complex;

D O I：

10.1016/S0277-5387(98)00138-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two series of trinuclear iron(III) carboxylate complexes with long alkyl chains, [Fe3O(O2CR)(6)L-3]NO3 where L=H2O or py (pyridine), were prepared. Powder X-ray diffraction patterns of each series suggested that the aqua series has a double-layer structure and the pyridine series has a single-layer structure. The single crystal X-ray structure determination of [Fe3O(O2CC13H27)(6)(py)(3)]NO3 revealed that the compound forms a single-layer structure with the interlamellar orientation of alkyl chains being arranged alternately to those of adjacent layers. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3507 / 3514

页数：8

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